SYNTHESIS OF CARBON NANOTUBES ON A SHUNGITE SUBSTRATE AND THEIR USE FOR LITHIUM–SULFUR BATTERIES

A shungite mineral has been used as a support material of catalyst particles to synthesize multiwalled carbon nanotubes (MWCNTs). Raman spectroscopy enabled us to follow the formation of MWCNTs. The morphology of synthesized MWCNTs was investigated by a scanning electron microscope and a transmission electron microscope. As a result of simple heat treatment at 300^o C for 3 h in an inert atmosphere, a novel sulfur/multiwalled carbon nanotubes/polyacrylonitrile (S/MWCNT/PAN) composite was synthesized. These methods of obtaining MWCNTs and S/MWCNT/PAN composite based on heat treatment possess the advantages of simplicity and low cost. The introduction of MWCNTs into the composite gives a highly conductive and mechanically flexible framework with an enhanced electronic conductivity and the ability to absorb polysulfides between the Li anode and cathode, which leads to an enhanced cyclability and a higher coulombic efficiency. The cell with this S/MWCNT/PAN ternary composite cathode demonstrates a stable reversible specific discharge capacity of 800 mA  ⋅ h ⋅ g –1 after 50 cycles at a battery C-rate of 0.2 C
  Автор:  Temirgaliyeva T. S. ,Nazhipkyzy M., Nurgain A. , Mansurov Z. A. , Bakenov Zh. B.
Ключевые слова:  multiwalled carbon nanotubes, lithium–sulfur batteries, composite, CVD
Стр:  1365