DETERMINATION OF THE MOLECULAR CHARACTERISTICS OF POLYOLEFINS WITH THE USE OF THE TOMS EFFECT
V. N. Manzhai,a L. G. Echevskaya,b A. V. Ilyushnikov,a A. Z. Aisheva,a V. A. Zakharov,b and M. A. Mats'kob UDC 532.135:539.199 The interrelation between the physicochemical properties of macromolecules and the hydrodynamic parameters of a turbulent flow of diluted polymer solutions in a cylindrical channel has been analytically determined. The possibility of estimating of the molecular characteristics of high-molecular polymers with the use of the turborheometric method has been considered. The antiturbulence efficiency of polyhexane used in energy-conserving technologies of pipeline transport of hydrocarbon materials has been analyzed on the basis of comparison of the molecular masses of polymers determined by different methods. aInstitute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akademicheskii Ave., Tomsk, 634021, Russian; bG. K. Boreskov Catalysis Institute, Siberian Branch of the Russian Academy of Sciences, 5 Akad. Lavrent'ev Ave., Novosibirsk, Russia; email: mang@ipc.tcs.ru; echev@catalysis.nsc.su. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 79, No. 1, pp. 162-166, January-February, 2006. Original article submitted July 30, 2004.