Recycling of low-density polyethylene waste for synthesis of carbon nanotubes

The authors have presented results of synthesis of carbon nanotubes from low-density polyethylene. The synthesis was carried by thermal destruction of the polyethylene in a chemical-vapor-deposition unit. The process of decomposition of the polyethylene and the synthesis of carbon nanotubes were implemented in one stage in a triple-fi red furnace for chemical vapor deposition. Consideration has been given to the infl uence of temperature on the decomposition products of polyethylene in the range of temperatures 450–550^o C. The gas- and vaporphase decomposition products of polyethylene, obtained at different temperatures, were investigated by the infrared spectroscopy method. It has been established that the necessary and suffi cient temperature of decomposition of polyethylene is 450^o C. Carbon nanotubes were grown on a catalyst that represented cenospheres impregnated with a ferrous nitrate solution. On exposure to high temperatures, ferrous nitrate decomposes to form pure iron particles on the cenospheric surface, which are active sites of growth of carbon nanotubes. The formation of iron particles on the cenospheric surface upon the impregnation with ferrous nitrate and thermal treatment is confi rmed by the results of x-ray phase analysis. A semiquantitative analysis shows that the content of iron in the total catalysts mass amounts to about 2.3%. The synthesis gives rise to carbon nanotubes with diameters of 50–60 nm on the cenospheric surface. Thus, it has been shown that carbon nanotubes can be synthesized from low-density polyethylene waste.
The authors have presented results of synthesis of carbon nanotubes from low-density polyethylene. The synthesis was carried by thermal destruction of the polyethylene in a chemical-vapor-deposition unit. The process of decomposition of the polyethylene and the synthesis of carbon nanotubes were implemented in one stage in a triple-fi red furnace for chemical vapor deposition. Consideration has been given to the infl uence of temperature on the decomposition products of polyethylene in the range of temperatures 450–550^o C. The gas- and vaporphase decomposition products of polyethylene, obtained at different temperatures, were investigated by the infrared spectroscopy method. It has been established that the necessary and suffi cient temperature of decomposition of polyethylene is 450^o C. Carbon nanotubes were grown on a catalyst that represented cenospheres impregnated with a ferrous nitrate solution. On exposure to high temperatures, ferrous nitrate decomposes to form pure iron particles on the cenospheric surface, which are active sites of growth of carbon nanotubes. The formation of iron particles on the cenospheric surface upon the impregnation with ferrous nitrate and thermal treatment is confi rmed by the results of x-ray phase analysis. A semiquantitative analysis shows that the content of iron in the total catalysts mass amounts to about 2.3%. The synthesis gives rise to carbon nanotubes with diameters of 50–60 nm on the cenospheric surface. Thus, it has been shown that carbon nanotubes can be synthesized from low-density polyethylene waste.
Author:  G. T. Smagulova, N. Vassilyeva, B. B. Kaidar, N. Yesbolov, N. G. Prikhod′ko, Zh. Supiyeva, M. T. Artykbaeva, Z. A. Mansurov
Keywords:  carbon nanotubes, low-density polyethylene, decomposition, cenospheres, iron, infrared spectroscopy
Page:  431-436